The unit performs elemental analysis on solution and solid samples, either by Solution ICP-MS & -AES, an Elemental Analyser to measure CHNS, XRF for major oxides and minor elements in rock or soil samples, and LA ICP-MS to measure whole-rock or in-situ mineral trace elements, while the Geochronology division does single mineral U-(Th)-Pb dating by LA ICP-MS.
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Most of the elements on the periodic table, with the exception of C, H, O, N, the halides & inert gasses can be analysed, in the concentration range of hundreds of mg/L to ng/L. Major and minor elements down to mid-ppb values are measured on a Thermo ICap 6200 ICP-AES, while ultra-trace analysis is done on an Agilent 7900 ICP-MS or Agilent 8800 QQQ ICP-MS. Data is quantified with calibration solutions prepared from NIST traceable standards, and quality control procedures according to US EPA guidelines are followed to ensure accuracy of data. Samples can be prepared by the client, or we can do a microwave digestion on a large variety of samples.
Laser Ablation ICP-MS
Trace element analysis
A Resolution M-50-LR Excimer laser ablation system is connected to an Agilent 7700 ICP-MS for most of the trace element analysis, using spot sizes between 60 and 200µm. Trace elements in bulk rock samples are analysed on polished mounts prepared from XRF fusions. Individual mineral grains can also be mounted and polished for analysis. Mounted and polished NIST standards and certified reference materials are used for quantification, using standard bracketing. Data is processed using either Iolite or Glitter software.
We offer clients from industry and academia the possibility of dating in situ and mounted single grain zircon samples as well as other accessory minerals (e.g. rutile, monazite) using an ASI Resolution M-50-SE Excimer laser coupled to a Thermo Element 2 SF SC ICP-MS.
Most of our recent work has focused on zircon and monazite dating applied to detrital, igneous and metamorphic studies, but we are also very interested in developing new methods and reference materials for dating other accessory phases (e.g. rutile, apatite, baddeleyite, xenotime, allanite).
The analytical set-up and the high spatial resolution approach we employ allow us to analyse up to 3 detrital zircon samples per day and resolve intra-grain zircon age domains down to the 20 micron scale.
Samples can be submitted as polished thin section/grain mounts or heavy mineral concentrates. In the latter case CAF staff will mount, polish and image (as required) the sample at an additional cost on our SEM (equipped with SE, BS and CL detectors) imaging facilities. All samples submitted as polished mounts will have to be prepared according to our guidelines and can also be imaged at our facilities. A mineral separation service is not currently provided by CAF, but we can provide training for researchers to perform their own mineral separation.
Clients are welcome to set up their own U-(Th)-Pb analytical sequences after all the instrumentation has been optimised by a CAF scientist, who will also perform the data reduction and final quality control.
Training in running the instruments, data reduction and interpretation is provided to post-doctoral, PhD and MSc students who have geochronology focussed projects and who will spend much of their project working in our laboratories. Such projects will have a CAF staff member from the geochronology division as an official supervisor on the project. Only fully trained post graduate students and established geochronologists are entitled to reduce the data, with final quality control by CAF staff. The decision as to who constitutes this category of users rests solely with the manager of the division.
Different industry and academic rates apply.
X-ray Fluorescence Spectrometry (XRF)
XRF is ideal for rapid and accurate whole bulk elemental analysis in rock or soil samples. The gas-flow proportional counting detector and scintillation detector, or a combination of the two, are used to cover the elements fluorine to uranium. Major elements are analysed on a fused glass bead and trace elements are analysed on a powder briquette. A wide range of international (NIST®) and national (SARM®) standards is used in the calibration procedures and quality control (precision and accuracy) for both major and trace element analyses. Detection limits for the elements quoted, depending on the matrix (combination of elements present), are typically 0.5 ppm. Loss on Ignition (LOI) is a test used in XRF major element analysis which consists of strongly heating a sample of the material at a specified temperature, allowing volatile substances to escape or oxygen is added, until its mass ceases to change. The L.O.I. is made of contributions from the volatile compounds H2O+, OH-, CO2, F, Cl, S; in parts also K, Na (if heated for too long); or alternatively added compounds O2 (oxidation, e.g. FeO to Fe2O3), later CO2 (CaO to CaCO3). In pyro-processing and the mineral industries such as lime, calcined bauxite, refractories or cement manufacture, the loss on ignition of the raw material is roughly equivalent to the loss in mass that it will undergo in a kiln, furnace or smelter.
An Elementar Vario EL Cube Elemental Analyzer has just been installed, which can measure C, H, N & S in a variety of samples, including soil, pharmaceutical, animal tissue, food & bio-fuel, with sample sizes from 1mg to ~ 1g.
Protein determination can be done by applying a correction factor to the measured nitrogen content of your food or animal feed sample. This is much quicker than the traditional Kjeldahl method. At the same time you will also obtain C, H and S values, as the instrument always measures all 4 elements.
Sample preparation for EA
We can only assist with drying of your samples if needed, you need to ensure the samples were appropriately prepared depending on the sample type.